Ӱ푶��Ȱl(f��)��ܵ��ؼ��M�ķ��

��r�g��2009-09-07 17:26 ��Դ�� : ��x��2094

ժҪ:��(y��ng)��ĝ�ȼ��(y��ng)��(y��ng)��ĽY(ji��)��(g��u)��ؾ��Ӱ푶��Ȱl(f��)��ܵ��,��ᘌ��@Щ��،��l(f��)��M�и��M,��ʹ��ʹ�Ãrֵ��

�P(gu��n)�I�~:��Ȱl(f��)��Ӱ��ظ��M

��

��W(xu��)��Ȱl(f��)��һ�N��û��W(xu��)ԭ��M�л��W(xu��)��(y��ng)��ɶ��ȵ��b��,��ܰ��(y��ng)��ܺ��O(sh��)��ʹ��,��@��ߛQ��˶��Ȱl(f��)��g(sh��)ˮƽ�Ƿ�(y��u)��,��Ƿ��Ќ��Ãrֵ�Ć��}��Ŀǰ��(n��i)��õ��c———�}�Ṥˇ�Ļ��W(xu��)��Ȱl(f��)��ܝM��Ñ��Ҫ��,��һ��кܺ�ʹ��ƏVǰ;��b��,��ǣ��ڶ��Ȱl(f��)��ܵ��(y��ng)��ĝ��,��(y��ng)��,��(y��ng)��Y(ji��)��(g��u)��ص�Ӱ푣��D(zhu��n)��ʺ͵��,��нY(ji��)�Ϲ��H,��Ӱ푶��Ȱl(f��)��M��˷��ӑՓ��(y��ng)��NaClO3�D(zhu��n)��ʼ�ClO2��ʵ��Ҫ��Ƿ��(y��ng)��ȼ��ᮔ(d��ng)��,��NaClO3��Һ��ȣ�,��Լ��(y��ng)��(y��ng)��Y(ji��)��(g��u)��,��

1��Ȱl(f��)��Ĺ��ԭ��

��c———�}�Ṥˇ��(y��ng)ʽ��£�

��(y��ng)��NaClO3+2HCl→ClO2+0.5Cl2+NaCl+H2O

��(y��ng)��NaClO3+6HCl→3Cl2+NaCl+3H2O

��σɂ��ʽ,��NaClO3��Ҫ��һ��±�Cl-��߀ԭ��߀ԭ�D(zhu��n)��ClO2��Cl2��HCl��߀ԭ��,��ṩ��(y��ng)��Ҫ��l��,��H��ɵķ��(y��ng)��ȫ��(y��ng)��B(t��i)��ɣ�Ҳ��ǰ��(y��ng)��B(t��i)��,��(y��ng)�͸��(y��ng)֮�g��ĳһ�N��B(t��i)��M�е�,��

2Ӱ�ClO2�l(f��)��ܵ��Ҫ��

2.1��(y��ng)��NaClO3��

һ�㻯�W(xu��)��(y��ng)�У��߷��(y��ng)��Ȼ򽵵��ȶ��ڷ��(y��ng)��﷽��M��,��NaClO3��Һ��^��,��(y��ng)��NaCl�ښ�Һ�еĝ��(y��ng)Ҳ�ߣ��ڷ��(y��ng)��Ͷˎ��ɽY(ji��)��,��ɹ�·��,��

2.2�ᮔ(d��ng)��ȡ�߀ԭ��

NaClO3��Һ��_��һ��ᮔ(d��ng)��,��(y��ng)�D(zhu��n)��ʺܵ�,��ٶȺ��߀ԭ��Cl-��,��NaClO3�D(zhu��n)��ʵ�,��^�࣬��(y��ng)��򸱷��(y��ng)��ƫ��,��mȻNaClO3�D(zhu��n)��ʸ�,��ClO2��ʵ͡�

2.3��(y��ng)��

һ�㷴��(y��ng)��͉��ɚ��w�a(ch��n)��ķ��M��,��Ȱl(f��)��ķ��(y��ng)��]ϵ�y(t��ng)��͉��ɚ��w�a(ch��n)��ķ��M��,��

2.4��(y��ng)��Y(ji��)��(g��u)

��ڻ��W(xu��)��(y��ng)�ܷ��O(sh��)Ӌ��ˇҪ��M��,��(y��ng)��ĽY(ji��)��(g��u)�O(sh��)Ӌ��Ҫ��Ҫ׌��(y��ng)��ĽY(ji��)��(g��u)��ܝM�㷴��(y��ng)��ˇ�l��,��練��(y��ng)��M��λ�á��ʽ,��λ��,��ʽ��(y��ng)��ڷ��(y��ng)��(n��i)��Ӡ�B(t��i),��Ҫ�Ӊ��p��ķ�ʽ,��(y��ng)��ĽY(ji��)��(g��u)�O(sh��)Ӌ��x��ʹ��(y��ng)�^��,��C��(y��ng)�^��_��D(zhu��n)��ʻ��,��߀ʹ��O(sh��)��кܺõ�ʹ��ܣ��ȫ��ɿ�,��ʵͣ�,��

3ClO2�l(f��)��ܵĸ��M��ʩ

3.1��(y��ng)��NaClO3
��ȡ��ᮔ(d��ng)��c߀ԭ��һ��õĹ��I(y��)�ϳ��}��,��30%��,��(d��ng)��ȴ�s11��}��ڷ��(y��ng)�е��,��ṩ��(y��ng)��Ҫ��ᮔ(d��ng)��,��߀ԭ��ڴ_��(y��ng)��ˇ�l��r��(y��ng)��]��,��ᮔ(d��ng)��ȸߌ��NaClO3�D(zhu��n)��,��߀ԭ��^�ߌ��ClO2��@�ɷ��,��

��(j��ng)һϵ�Ѓ�(y��u)��ԇ�Y(ji��)��NaClO3��Һ��27%��,��NaClO3��Һ�c�}��1��1.2��1.5��m��ڴ˗l��¿ɵõ��(y��u)��NaClO3�D(zhu��n)��ʣ��95%��ClO2��ʣ��70%��,��Ҝؗl��NaCl��нY(ji��)��ܵ�,��

3.2��(y��ng)��

��c�c�}�ᷴ��(y��ng)��ClO2,��Cl2��߾��ɱ��w,��һ��п��Ա��İ�ȫ�Ƕȁ��v,��ؓ��ڰ�ȫ��,��(j��ng)��ԇ�l(f��)�F(xi��n)��l��ͬؓ��(y��ng)��(y��ng)NaClO3��D(zhu��n)��ʴ�3%��,��ClO2��ʴ�2%��,��ԭ��Ҫ��ڷ��(y��ng)�wϵ��,��wጷ��٣��׃?n��i)�,��?y��ng)��|��(y��ng)��ĕr�g��L�ȷ��,��˷��(y��ng)�D(zhu��n)��ʼ��Ӱ푣��(j��)��(y��ng)��Y(ji��)��(g��u),��ԭ��Ӌ��}�Ӊ��,��ע�뷴��(y��ng)��ڷ��(y��ng)��(n��i)�ػ�ϔ��b�ó��}��,��ʹ�÷��(y��ng)��ڷ��(y��ng)��(n��i)�Ļ��Ч��,��Ч�ر��C��(y��ng)��D(zhu��n)��ʺ͵��ʡ�

3.3��(y��ng)��Y(ji��)��(g��u)

��(y��ng)��O(sh��)Ӌ��,��(j��)��W(xu��)��(y��ng)��O(sh��)Ӌԭ��,��Լ��c———�}�ᷴ��(y��ng)��ˇ�l��(y��ng)�^��c��Ҫ��,��ڽY(ji��)��(g��u)�ϲ��Һ��Mԭ��ϳ��a(ch��n)Ʒ��ʽ,��ጷŚ⎧��όӷ��(y��ng)Һ��ӣ�ͨ�^��(y��ng)��(n��i)��û�ϔ��b��,��MҺ�w��ֻ��,��}��ʽ��ӷ�ʽʹ��(y��ng)��ڷ��(y��ng)��(n��i)��һ��^ƽ��(w��n)��ͣ��^�̣��F(xi��n)��(y��ng)��Ɔμ��(y��ng)��п��ܳ��F(xi��n)�ķ��(y��ng)��(y��ng)��ų��(y��ng)��֮��ֱ��F(xi��n)��,��Ч�ر��C��(y��ng)��ͣ��(y��ng)�r�g�ͷ��(y��ng)��ϵ��D(zhu��n)��,��

4��Ӱ��صĸ��M��

�l(f��)��ԭ��Һ��Ӌ��ݔ��O(sh��)�䣬Ӌ��õ��ã�һ��Ӌ��ݔ��ԭ��Һ��,��ʹ�䶨��ע��(y��ng)��(n��i),��Cԭ�ϰ��ɷ��(y��ng)��ṩҺ�w��ӵĉ��,��ʹ�䷴��(y��ng)��ֱ�Ӽ�ע��ܾW(w��ng)ˮ�w��,��Ӌ��L��\�еĄ��O(sh��)�䣬��Ʒ�|(zh��)�É�,��Ƕ��Ȱl(f��)��ܷ��L��,��(w��n)��\�е��P(gu��n)�I,��Ӌ��Æ��y�ܷ�Ȧ��g,��׃�ͣ��ܷⲻ��,��©��,��(j��ng)��F(xi��n)��ԭ�ϵ��r��Q�ܷ�ȦҲ��ڲ�ж��y�Ć��},��x�ø��Q�ܷ�Ȧ��Y(ji��)��(g��u)��εĆ��yӋ��,��ēQ�ܷ�Ȧ,��ʹ�ɿ��Դ��ߣ��ʽ��,��(y��ng)��ϵ��x�񣺰��շ��(y��ng)��ˇ�l��@��D(zhu��n)��ʺ͵��,��ʹ��(y��ng)��l(f��)�]�ɿ��ʹ��ܡ��P(gu��n)�Iȡ�Q�ڷ��(y��ng)��Ĳ��|(zh��)��Ͷˎ�ܵĲ��|(zh��),��(j��ng)�^��ԇ�,��x��N��(y��ng)��ڸ��,��ClO2��ȡ��߉��l��²��_��͸��g,��ܿ��F(xi��n)й©�F(xi��n)��,��PVC��Ϸ��(y��ng)��Љ��^��䓼ӹ��Ҳ��ClO2�ĸ��g,��ķ��ϩ��ϼӹ��B��ܷ�̎��F(xi��n)й©�ȬF(xi��n)��,��˱�횲��Ï��͸��g��طN��ٲ��ϣ��Ч��Q�͸��͉�Ҫ��,��K��⁻��ϱ��滯�W(xu��)��g,��Ч�ؽ�Q��y�}��

5�Y(ji��)Փ

ͨ�^��(y��ng)��,��(y��ng)��,��(y��ng)��Y(ji��)��(g��u)��|(zh��)��صķ��Y(ji��)��˶��Ȱl(f��)��ĸ��M��ʩ,��(j��)��Փ��ʹ��ԇ��C��ڴ_��˃�(y��u)��ķ��(y��ng)��,��ᮔ(d��ng)��ȡ�߀ԭ��Լ��(y��ng)��Y(ji��)��(g��u)��ķ��(y��ng)ͣ��r�g��,��(y��u)��Ĺ�ˇ��ʹ��(y��ng)�M��ܰ��ӽ��(y��ng)�^��M��,��@��ClO2��ʺ�NaClO3�D(zhu��n)��ʣ��Ķ��c—�}�ᷴ��(y��ng)�wϵ��H��(y��ng)�õĿɿ��,��Է��ˈԌ��Փ��A(ch��),��

��īI
1R.S.��R��W.�Uˮ̎��Փ.��Ї��I(y��)��磬1985,��412��417.
2��.ˮ̎�턩��(y��ng)��փ�.��W(xu��)��I(y��)��,��2000��352��389.
3κ��|,��p,��꣬��.��:�Ї��I(y��)��,��1989,��168��190.
4��ʿ,��ͬ��.��V��.��:�Ї��I(y��)��磬1985,��67��75.
5H.�ݸ�.��.��I(y��)�ܷ⼼�g(sh��).��W(xu��)��I(y��)��,��1988��52��68.

����D(zhu��n)�d��ǳ��ڂ��f��Ϣ֮Ŀ��,��Ё�Դ��ע�e�`��ַ��ĺϷ��(qu��n)��,��Ո��߳֙�(qu��n)��C��c��W(w��ng)(li��n)ϵ��҂��r��,��h��,��x�x��